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JEE Mains · Chemistry · STD 12 -1. Solution and colligative properties

If a compound \(Ab\) dissociates to the extent of \(75 \,\%\) in an aqueous solution, the molality of the solution which shows a \(2.5\, K\) rise in the boiling point of the solution is ......  molal. (Rounded-off to the nearest integer) \(\left[ K _{ b }=0.52 \,K \,kg\, mol ^{-1}\right]\)

  1. A \(4\)
  2. B \(3\)
  3. C \(6\)
  4. D \(5\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(3\)

Step-by-step Solution

Detailed explanation

\(\alpha=0.75, n =2\) \(i =1-\alpha+ n \alpha=1-0.75+2 \times 0.75=1.75\) \(\Delta T _{ b }= ik _{ b } m\) or, \(2.5=1.75 \times 0.52 \times m\) or, \(m =\frac{2.5}{1.75 \times 0.52}=2.74\) \(\therefore\) nearest integer answer will be \(3\)
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