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JEE Mains · Chemistry · STD 12 - 4. d and f- block elements

Identify correct statements from below: \(A\). The chromate ion is square planar. \(B\). Dichromates are generally prepared from chromates. \(C\). The green manganate ion is diamagnetic. \(D\). Dark green coloured \(\mathrm{K}_2 \mathrm{MnO}_4\) disproportionates in a neutral or acidic medium to give permanganate. \(E\). With increasing oxidation number of transition metal, ionic character of the oxides decreases. Choose the correct answer from the options given below:

  1. A \(B, C, D\) only
  2. B \(A, D, E\) only
  3. C \(A, B, C\) only
  4. D \(B, D, E\) only
Verified Solution

Answer & Solution

Correct Answer

(D) \(B, D, E\) only

Step-by-step Solution

Detailed explanation

\(A\). \(\mathrm{CrO}_4{ }^{2-}\) is tetrahedral \(B\). \(2 \mathrm{Na}_2 \mathrm{CrO}_4+2 \mathrm{H}^{+} \rightarrow \mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_{/}+2 \mathrm{Na}^{+}+\mathrm{H}_2 \mathrm{O}\) \(C\). As per \(NCERT\), green manganate is paramagnetic with \(1\)…
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