JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry
Dissociation of a gas \(A _2\) takes place according to the following chemical reactions. At equilibrium, the total pressure is 1 bar at 300 K .
\(A_2(g) \rightleftharpoons 2 A(g)\)
The standard Gibbs energy of formation of the involved substances has been provided below:
| Substance | \(\Delta G _{ t }^{\circ} / kJ mol ^{-1}\) |
| \(A _2\) | -100.00 |
| \(A \) | -50.832 |
(Nearest integer).
[Given: R =8 J \(mol ^{-1} K^{-1}\), log 2 = 0.3010, log 3 = 0.48]
- A 30
- B 33
- C 35
- D 38
Answer & Solution
Correct Answer
(B) 33
Step-by-step Solution
Detailed explanation
\(-1.664 \times 10^3=-8.3 \times 300 \ln K_{ p }\) \(\ln K _{ p }=0.693\) \(K_{ p }=2\) \(2=\frac{4 \alpha^2 P _0}{1-\alpha^2}\) \(\alpha=\frac{1}{\sqrt{3}}\) \(\alpha=\left(\frac{100}{3} \times 10^{-2}\right)^{1 / 2}\) \(=\left(33.33 \times 10^{-2}\right)^{1 / 2}\)
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- Arrange the following labelled hydrogens in decreasing order of acidity
JEE Mains 2020 Medium - The reagent needed for converting \(Ph - C \equiv C - Ph \to \)
JEE Mains 2014 Hard - In which of the following order the given complex ions are arranged correctly with respect to their decreasing spin only magnetic moment? \((i)\) \(\left[ FeF _{6}\right]^{3-}\) \((ii)\) \(\left[ Co \left( NH _{3}\right)_{6}\right]^{3+}\) \((iii)\) \(\left[ NiCl _{4}\right]^{2-}\) \((iv)\) \(\left[ Cu \left( NH _{3}\right)_{4}\right]^{2+}\)JEE Mains 2021 Hard
- Given below are two statements : Statement \(I :\) The esterification of carboxylic acid with an alcohol is a nucleophilic acyl substitution. Statement \(II :\) Electron withdrawing groups in the carboxylic acid will increase the rate of esterification reaction. Choose the most appropriate optionJEE Mains 2022 Medium
- The predominant intermolecular forces present in ethyl acetate, a liquid, areJEE Mains 2020 Hard
- From the given list, the number of compounds with \(+4\) oxidation state of Sulphur _______.
\(\mathrm{SO}_3, \mathrm{H}_2 \mathrm{SO}_3, \mathrm{SOCl}_2, \mathrm{SF}_4, \mathrm{BaSO}_4, \mathrm{H}_2 \mathrm{~S}_2 \mathrm{O}_7\)JEE Mains 2024 Hard
More PYQs from JEE Mains
- Consider the ions/molecule \(O _{2}^{+}, O _{2}, O _{2}^{-}, O _{2}^{2-}\) For increasing bond order the correct option is ..... .JEE Mains 2022 Easy
- If the series limit frequency of the Lyman series is \(v_L\), then the series limit frequency of the \(P\)-fund series isJEE Mains 2018 Medium
- A chromatography column, packed with silica gel as stationary phase, was used to separate a mixture of compounds consisting of \((A)\) benzanilide \((B)\) aniline and \((C)\) acetophenone. When the column is eluted with a mixture of solvents, hexane: ethyl acetate \((20: 80),\) the sequence of obtained compoundsJEE Mains 2020 Hard
- Which one of the following lanthanoids does not form \(MO _{2} ?\) [\(M\) is lanthanoid metal]JEE Mains 2021 Easy
- Let a circle passing through \((2,0)\) have its centre at the point \((\mathrm{h}, \mathrm{k})\). Let \(\left(\mathrm{x}_{\mathrm{c}}, \mathrm{y}_{\mathrm{c}}\right)\) be the point of intersection of the lines \(3 x+5 y=1\) and \((2+c) x+\) \(5 c^2 y=1\). If \(h=\lim _{c \rightarrow 1} x_c\) and \(k=\lim _{c \rightarrow 1} y_c\), then the equation of the circle is :JEE Mains 2024 Hard
- Two slits are \(1 \mathrm{~mm}\) apart and the screen is located \(1 \mathrm{~m}\) away from the slits. A light wavelength \(500 \mathrm{~nm}\) is used. The width of each slit to obtain \(10\) maxima of the double slit pattern within the central maximum of the single slit pattern is _______ \(\times 10^{-4} \mathrm{~m}\)JEE Mains 2024 Hard