JEE Mains · Chemistry · STD 11 - 6.1. Equilibrium - 1 (chemical Equilibrium)
Use the following data :
| Substance | \(\frac{\Delta_{ f } H ^{\ominus}(500 K)}{ kJ mol ^{-1}}\) | \(\frac{ S ^{\ominus}(500 K)}{ JK ^{-1} mol^{-1}}\) |
| \(AB ( g )\) | 32 | 222 |
| \(A _2(g)\) | 6 | 146 |
| \(B _2(g)\) | X | 280 |
One mole each of \(A _2(g)\) and \(B _2(g)\) are taken in a 1L closed flask and allowed to establish the equilibrium at 500 K .
\(A _2(g)+ B _2(g) \rightleftharpoons 2 AB ( g )\)
The value of in \(x\left( kJ mol ^{-1}\right)\) is ............ (Nearest integer)
(Given: \(\log K =2.2 R =8.3 JK ^{-1} mol^{-1}\) )
- A 60
- B 70
- C 80
- D 90
Answer & Solution
Correct Answer
(B) 70
Step-by-step Solution
Detailed explanation
\(A _2+ B _2 \xrightarrow{500 K} 2 AB \log K =2.2\) \(\Delta H ^{\circ}=(2 \times 32)-(6+ x )=(58- x ) kJ\) \(\Delta S ^{\circ}=(2 \times 222)-(146+280)=18\) Joule \(\Delta G ^{\circ}=- RT \ln K\) \(\Delta G ^{\circ}=-\frac{8.314 \times 500 \times 2.2 \times 2.303}{1000}\)…
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- Given below are two statements. One is labelled as Assertion \(A\) and the other is labelled as Reason \(R\). Assertion \(A\): Amylose is insoluble in water. Reason \(R\): Amylose is a long linear molecule with more than \(200\) glucose units. In the light of the above statements, choose the correct answer from the options given below.JEE Mains 2022 Medium
- Consider the above reaction. The number of \(\pi\) electrons present in the product ' \(P\) ' is ...... .
JEE Mains 2022 Easy - The descending order of basicity of following amines is _______.

Choose the correct answer from the options given below :JEE Mains 2025 Hard - Wilkinson catalyst isJEE Mains 2019 Hard
- Consider the following chemical reaction. \(CH \equiv CH\xrightarrow[{{\text{(2) CO , HCl , AlC}}{{\text{l}}_3}}]{{{\text{(1) Red hot Fe tube, 873 K}}}}\) Product The number of \(sp ^{2}\) hybridized carbon atom(s) present in the product is ..........JEE Mains 2021 Medium
- The spin only magnetic moment of \(\left[ Mn \left( H _2 O \right)_6\right]^{2+}\) complexes is \(........B.M.\) (Nearest integer)(Given : Atomic no. of \(Mn\) is \(25\) )JEE Mains 2023 Medium
More PYQs from JEE Mains
- Two ideal polyatomic gases at temperatures \(T _{1}\) and \(T _{2}\) are mixed so that there is no loss of energy. If \(F _{1}\) and \(F _{2}, m _{1}\) and \(m _{2}, n _{1}\) and \(n _{2}\) be the degrees of freedom, masses, number of molecules of the first and second gas respectively, the temperature of mixture of these two gases isJEE Mains 2021 Hard
- The area of the region in the first quadrant inside the circle \(x^2+y^2=8\) and outside the parabola \(\mathrm{y}^2=2 \mathrm{x}\) is equal to :JEE Mains 2024 Hard
- If the coefficients of the three successive terms in the binomial expansion of \((1 + x)^n\) are in the ratio \(1 : 7 : 42,\) then the first of these terms in the expansion isJEE Mains 2015 Hard
- Let \(\overrightarrow{\mathrm{OA}}=2 \overrightarrow{\mathrm{a}}, \overrightarrow{\mathrm{OB}}=6 \overrightarrow{\mathrm{a}}+5 \overrightarrow{\mathrm{b}}\) and \(\overrightarrow{\mathrm{OC}}=3 \overrightarrow{\mathrm{b}}\), where \(O\) is the origin. If the area of the parallelogram with adjacent sides \(\overrightarrow{\mathrm{OA}}\) and \(\overrightarrow{\mathrm{OC}}\) is \(15\) sq. units, then the area (in sq. units) of the quadrilateral \(\mathrm{OABC}\) is equal to :JEE Mains 2024 Medium
- Two closed vessels of same volume are joined through a narrow tube and both vessels are filled with air of pressure \(90\) kPa and temperature \(400\) K. Keeping the temperature of one vessel constant at \(400\) K the second vessel temperature is raised to \(500\) K. The final pressure in the vessels is _______ kPa.JEE Mains 2026 Medium
- Let \(x=x(y)\) be the solution of the differential equation \(2 y \,e^{x / y^{2}} d x+\left(y^{2}-4 x e^{x / y^{2}}\right) d y=0\) such that \(x(1)=0\). Then, \(x(e)\) is equal toJEE Mains 2022 Hard