JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry
The reaction \(MgO(s) + C(s) \to Mg(s) + CO(g)\), for which \(\Delta _r{H^o} = + 491.1\,kJ\,mo{l^{ - 1}}\) and \(\Delta _r{S^o} = 198.0\,Jk^{-1}\,mo{l^{ - 1}}\) is not feasible at \(298\, K\). Temperature above which reaction will be feasible is.....\(K\)
- A \(2040.5\)
- B \(1890\)
- C \(2480.3\)
- D \(2380.5\)
Answer & Solution
Correct Answer
(C) \(2480.3\)
Step-by-step Solution
Detailed explanation
In order to be spontaneous \(\Delta G^o\) should be \(-ve\) \(\Delta {G^o} = \Delta {H^o} - T\Delta {S^o}\) \(0 = 491.1 \times {10^3} - T \times 198\) \(T = \frac{{491100}}{{198}} = 2480\) If temp is above \(2480\,K\), the reaction will be spontaneous.
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