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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

\(C ( s )+ O _{2}( g ) \rightarrow CO _{2}( g )+400\; kJ\) \(C ( s )+\frac{1}{2} O _{2}( g ) \rightarrow CO ( g )+100 \;kJ\) When coal of purity \(60 \%\) is allowed to burn in presence of insufficient oxygen, \(60 \%\) of carbon is converted into \('CO'\) and the remaining is converted into \('CO _{2}\)\('\). The heat generated when \(0.6 \;kg\) of coal is burnt is

  1. A \(1600\; kJ\)
  2. B \(3200\; kJ\)
  3. C \(4400\; kJ\)
  4. D \(6600\; kJ\)
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Correct Answer

(D) \(6600\; kJ\)

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\(C ( S )+ O _{2}( g ) \rightarrow CO _{2}( g )+400\; kJ\) \(1\; g \;mole\) \(C ( s )+\frac{1}{2} O _{2}( g ) \rightarrow CO ( g )+100\; kJ \ldots (II)\) \(0.6 \times 1000\) \(=600 \;gm\) \(600 \times \frac{60}{100}\) (Pure Carbon) \(=360 \;gm =\frac{360}{12}=30 \;mole\) (Pure…
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