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JEE Mains · Chemistry · STD 12 - 9. Amines

An amine on reaction with benzenesulphonyl chloride produces a compound insoluble in alkaline solution. This amine can be prepared by ammonolysis of ethyl chloride. The correct structure of amine is

  1. B \(CH _{3} CH _{2} NH _{2}\)
  2. C \(CH _{3} CH _{2} CH _{2} NHCH _{3}\)
  3. D \(C{H_3}C{H_2}C{H_2}\mathop N\limits^H  - C{H_2}C{H_3}\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(C{H_3}C{H_2}C{H_2}\mathop N\limits^H  - C{H_2}C{H_3}\)

Step-by-step Solution

Detailed explanation

It has to be \(2^{\circ}\) amine because on reaction with benzene sulphonylchloride it gives water in soluble product. As it is formed by ammonolysis of ethylchloride, so it has to be \(R-NH-Et\) type.