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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

પ્રક્રિયા \(A(g) \to A(l)\) માટે \(\Delta H =  - 3RT\) છે. તો પ્રક્રિયા માટે સાચો સંબંધ જણાવો.

  1. A \(\Delta H = \Delta U \ne O\)
  2. B \(\Delta H = \Delta U = O\)
  3. C \(\left| {\Delta H} \right| < \left| {\Delta U} \right|\)
  4. D \(\left| {\Delta H} \right| > \left| {\Delta U} \right|\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(\left| {\Delta H} \right| > \left| {\Delta U} \right|\)

Step-by-step Solution

Detailed explanation

\(A(g) \to A(1)\) \(\Delta H = \Delta U + \Delta {n_g}RT\) Given, \(\Delta H = - 3RT\) Here \(\Delta {n_g} = {n_p} - {n_r} = 0 - 1 = - 1\) \(\Delta H = \Delta U - RT\) \( \Rightarrow - 3RT = \Delta U - RT\) \( \Rightarrow - 3RT + RT = \Delta U\) \( \Rightarrow - 2RT = \Delta U\)…
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