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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

જો \(100\,\) મોલ \(H_2O_2\) એ \(1\, bar\) and \(300\, K\) પર વિઘટન પામે તો \(1\) મોલ \(O_2(g)\) એ \(1\, bar\) દબાણ વિરુદ્ધ પ્રસરણ પામે ત્યારે થતુ કાર્ય ............\(kJ\) \(2{H_2}{O_2}(l) \rightleftharpoons {H_2}O(l) + {O_2}(g)\) \((R = 8.3\, JK^{-1}\, mol^{-1})\)

  1. A \(124.50\)
  2. B \(249\)
  3. C \(498\)
  4. D \(62.25\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(124.50\)

Step-by-step Solution

Detailed explanation

\(2{H_2}{O_2}(l) \leftrightarrow 2{H_2}O(l) + {O_2}(g)\) \(W = - {P_{ext}}(\Delta V) = - ({n_{{O_2}}})RT\) \(\because \,100\) mole \({H_2}{O_2}\) on decomposition give \(50\) mol \({O_2}\) \(\therefore \,W = - (50)(8.3)(300) = - 124500\,J\) \( = - 124.5\,kJ\)
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