JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
The number of isoelectronic species among \(Sc^{3+}\), \(Cr^{2+}\), \(Mn^{3+}\), \(Co^{3+}\) and \(Fe^{3+}\) is 'n'. If 'n' moles of AgCl is formed during the reaction of complex with formula \(CoCl_{3}(en)_{2}NH_{3}\) with excess of \(AgNO_{3}\), then the number of electrons present in the \(t_{2g}\) orbital of the complex is __________ .
- A 4
- B 6
- C 8
- D 10
Answer & Solution
Correct Answer
(B) 6
Step-by-step Solution
Detailed explanation
\(Sc ^{+3}\) 18 \(Cr ^{+2}\) 22 \(Mn ^{+3}\) 22 \(Co ^{+3}\) 24 \(Fe ^{+3}\) 23 \(Cr ^{2+}\) and \(Mn ^{3+}\) are isoelectronic \(n =2\) Complex is : \(\left[ Co ( en )_2 NH _3 Cl \right] Cl _2\) \(\Rightarrow Co ^{3+} \quad 3 d^6 \quad t _{2 g}^{2,2,2} \quad e _{ g }^{0,0}\)
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