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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

Given \(\left( i \right)\,2F{e_2}{O_3}\left( s \right) \to 4Fe\left( s \right) + 3{O_2}\left( g \right)\)          \({\Delta _r}{G^o} =  + 1487.0\,kJ\,mo{l^{ - 1}}\) \(\left( {ii} \right)\,2CO\left( g \right) + {O_2}(g) \to 2C{O_2}\left( g \right)\)         \({\Delta _r}{G^o} =  - 514.4\,kJ\,mo{l^{ - 1}}\) Free energy change, \(\Delta_rG^o\)  for the reaction \(\,2F{e_2}{O_3}\left( s \right) + 6CO\left( g \right) \to 4Fe\left( s \right) + 6C{O_2}\left( g \right)\) will be .....\(kJ\, mol^{-1}\)

  1. A \(-112.4\)
  2. B \(-56.2\)
  3. C \(-208\)
  4. D \(-168.2\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(-56.2\)

Step-by-step Solution

Detailed explanation

\((i)\,2F{e_2}{O_3}(s) \to 4Fe(s) + 3{O_2}(g);\) \({\Delta _r}{G^o} = + 1487.0\,kJ\,mo{l^{ - 1}}\) \((ii)\,2CO(g) + {O_2}(g) \to 2C{O_2}(g);\) \({\Delta _r}{G^o} = - 514.4\,kJ\,mo{l^{ - 1}}\) Multiple reaction \((ii)\) with \(3\),we get…
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