The bond energy (in \(\mathrm{kcal} \mathrm{mol}^{-1}\) ) of \(\mathrm{C}-\mathrm{C}\) single bond is approximately

The cyanide process of gold extraction involves leaching out gold from its ore with ${\mathrm{C}\mathrm{N}}^{-}$ in the presence of $\mathrm{Q}$ in water to form $\mathrm{R}$ . Subsequently, $\mathrm{R}$ is treated with $\mathrm{T}$ to obtain $\mathrm{A}\mathrm{u}$ and $\mathrm{Z}$ . Choose the correct option(s).

Which among the following statement(s) is (are) true for the extraction of aluminium from bauxite?

The pair(s) of diamagnetic ions is(are)

The wave function, ${\mathrm{\psi }}_{\mathrm{n},\mathrm{}\mathrm{l},\mathrm{}{\mathrm{m}}_{\mathrm{l}}}$ is a mathematical function whose value depends upon spherical polar coordinates $\left(\mathrm{r},\mathrm{}\mathrm{\theta },\mathrm{}\mathrm{\varphi }\right)$ of the electron and characterized by the quantum numbers $\mathrm{n},\mathrm{}\mathrm{l}$ and ${\mathrm{m}}_{\mathrm{l}}$ . Here $\mathrm{r}$ is the distance from the nucleus, $\mathrm{\theta }$ is colatitude and $\mathrm{\varphi }$ is azimuth. In the mathematical functions given in the Table, $\mathrm{Z}$is the atomic number and ${\mathrm{a}}_{\mathrm{o}}$ is Bohr radius

Column 1	Column 2	Column 3
(I) 1s orbital	\(\begin{array}{l}\text { (i) } \psi_{ n , 1, m_1} \\ \propto\left(\frac{ Z }{ a _{ o }}\right)^{\frac{3}{2}} e ^{-\left(\frac{ Zr }{ e _{ o }}\right)}\end{array}\)	(P)
(II) 2s orbital	(ii) One radial node	(Q) Probability density at the nucleus \(\propto \frac{1}{ a _{ o }^3}\).
(III) \(2 p _{ z }\) orbital	\(\begin{array}{l}\text { (iii) } \psi_{ n }, 1, m_{ l } \\ \propto\left(\frac{ Z }{ a _{ o }}\right)^{\frac{5}{2}} re ^{-\left(\frac{ Zr }{2 a _{ o }}\right)} \cos \theta\end{array}\)	(R) Probability density is maximum at the nucleus.
(IV) \(3 d_{ z }^2\) orbital	(iv) \(x y\)-plane is a nodal plane	(S) Energy needed to excite an electron from \(n =2\) state to \(n =4\) state is \(\frac{27}{32}\) times the energy needed to excite are electron from \(n =2\) state to \(n =6\) state.

For the given orbital in column 1, the only correct combination for any hydrogen-like species is

The desired product X can be prepared by reacting the major product of the reactions in LIST-I with one or more appropriate reagents in LIST-II.
(given, order of migratory aptitude: aryl > alkyl hydrogen)

	LIST-I		LIST -II
A)		P)	${\mathrm{I}}_2,\mathrm{NaOH}$
B)		Q)	$\left[\mathrm{Ag}{\left({\mathrm{NH}}_3\right)}_2\mathrm{OH}\right]$
C)		R)	Fehling solution
D)		S)	$\mathrm{H}\mathrm{C}\mathrm{H}\mathrm{O},\mathrm{N}\mathrm{a}\mathrm{O}\mathrm{H}$
		T)	$\mathrm{NaOBr}$

Which of the given statement(s) about \(\mathbf{N}, \mathbf{O}, \mathbf{P}\) and \(\mathbf{Q}\) with respect to \(\mathbf{M}\) is (are) correct?

Two beams of red and violet colours are made to pass separately through a prism (angle of the prism is \(60^{\circ}\) ). In the position of minimum deviation, the angle of refraction will be

An electron in a hydrogen atom undergoes a transition from an orbit with a quantum number $n_i$ to another quantum number $n_f$ . $V_i \text{and} V_f$ are the initial and final potential energies of the electron. If $\frac{V_i}{V_f}=6.25$ then the smallest $n_f$ is

If $\mathrm{I}=\frac{2}{\mathrm{\pi }}\underset{-\frac{\mathrm{\pi }}{4}}{\overset{\frac{\mathrm{\pi }}{4}}{\int }}\frac{\mathrm{d}\mathrm{x}}{\left(1+{\mathrm{e}}^{\mathrm{s}\mathrm{i}\mathrm{n}\mathrm{x}}\right)\left(2-\mathrm{c}\mathrm{o}\mathrm{s}2\mathrm{x}\right)}$ then find $27{\mathrm{I}}^2$ equals____

Let \(a\) and \(b\) be non-zero and real numbers. Then, the equation \(\left(a x^2+b y^2+c\right)\left(x^2-5 x y+6 y^2\right)=0\) represents

Some laws/processes are given in Column I. Match these with the physical phenomena given in Column II and indicate your answer by darkening appropriate bubbles in the \(4 \times 4\) matrix given in the ORS.

A hydrogen atom, initially at rest in its ground state, absorbs a photon of frequency \(v_1\) and ejects the electron with a kinetic energy of 10 eV . The electron then combines with a positron at rest to form a positronium atom in its ground state and simultaneously emits a photon of frequency \(v_2\). The center of mass of the resulting positronium atom moves with a kinetic energy of 5 eV . It is given that positron has the same mass as that of electron and the positronium atom can be considered as a Bohr atom, in which the electron and the positron orbit around their center of mass. Considering no other energy loss during the whole process, the difference between the two photon energies (in eV ) is \(\qquad\)