Which among the following statement(s) is (are) true for the extraction of aluminium from bauxite?

List-I contains various reaction sequences and List-II contains different phenolic compounds.
Match each entry in List-I with the appropriate entry in List-II and choose the correct option.

A tin chloride $\mathrm{Q}$ undergoes the following reactions (not balanced)
$\mathrm{Q}+\mathrm{C}{\mathrm{l}}^{-}\to \mathrm{X}$
$\mathrm{Q}+\mathrm{M}{\mathrm{e}}_3\mathrm{N}\to \mathrm{Y}$
$\mathrm{Q}+\mathrm{C}\mathrm{u}\mathrm{C}{\mathrm{l}}_2\to \mathrm{Z}+\mathrm{C}\mathrm{u}\mathrm{C}\mathrm{l}$
$\mathrm{X}$ is a monoanion having pyramidal geometry. Both $\mathrm{Y}$ and $\mathrm{Z}$ are neutral compounds. Choose the correct option(s).

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Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator automobiles.
A solution \(M\) is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixtrue is \(0.9\)
Given Freezing point depression constant of water \(\left(k^{\text {water }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\)
Freezing point depression constant of ethanol \(\left(k_f^{\text {ethanol }}\right)=2.0 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of water \(\left(k_b^{\text {water }}\right)=0.52 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of ethanol \(\left(k_b^{\text {ethanol }}\right)=1.2 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Standard freezing point of water \(=273 \mathrm{~K}\)
Standard freezing point of ethanol \(=155.7 \mathrm{~K}\)
Standard boiling point of water \(=373 \mathrm{~K}\)
Standard boiling point of ethanol \(=351.5 \mathrm{~K}\)
Vapour pressure of pure water \(=328 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Vapour pressure of pure ethanol \(=40 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Molecular weight of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\)
Molecular weight of ethanol \(=46 \mathrm{~g} \mathrm{~mol}^{-1}\)
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Question:
Water is added to the solution \(M\) such that the mole fraction of water in the solution becomes \(0.9\) The boiling point of this solutions is

In the chemical reaction between stoichiometric quantities of ${\mathrm{KMnO}}_4$ $\mathrm{KI}$ in weakly basic solution, what is the number of moles of ${\mathrm{I}}_2$ released for $4$ ${\mathrm{KMnO}}_4$ consumed?

For the elementary reaction $\mathrm{M}\to \mathrm{N}$, the rate of disappearance of $\mathrm{M}$ increases by a factor of $8$ upon doubling the concentration of $\mathrm{M}$. The order of the reaction with respect to $\mathrm{M}$ is

Match each of the diatomic molecules in Column I with its property/properties in Column II.

Column I	Column II
A. \(B _2\)	p. Paramagnetic
B. \(N_2\)	q. Undergoes oxidation
C. \(O _2^{-}\)	r. Undergoes reduction
D. \(O _2\)	s. Bond order
	t. Mixing of 's' and 'p' orbitals

The reaction of ${\mathrm{HClO}}_3$ with $\mathrm{HCl}$ gives a paramagnetic gas, which upon reaction with ${\mathrm{O}}_3$ produces

Three glass cylinders of equal height $\mathrm{H}=30\mathrm{}\mathrm{c}\mathrm{m}$ and same refractive index $\mathrm{n}=1.5$ are placed on a horizontal surface shown in figure. Cylinder $\mathrm{I}$ has a flat top, cylinder $\mathrm{I}\mathrm{I}$ has a convex top and cylinder $\mathrm{I}\mathrm{I}\mathrm{I}$ has a concave top. The radii of curvature of the two curved tops are same $\left(\mathrm{R}=3\mathrm{m}\right).$ If ${\mathrm{H}}_1,{\mathrm{H}}_2$ and ${\mathrm{H}}_3$ are the apparent depths of a point $\mathrm{X}$ on the bottom of the three cylinders, respectively, the correct statement(s) is/are

Two spherical planets \(P\) and \(Q\) have the same uniform density \(\rho\), masses \(M_{P}\) and \(M_{Q}\) and surface areas \(A\) and 4A respectively. A spherical planet \(R\) also has uniform density \(\rho\) and its mass is \(\left(M_{P}+M_{Q}\right)\). The escape velocities from the planets \(P, Q\) and \(R\) are \(V_{P}, V_{Q}\) and \(V_{R}\), respectively. Then

Among \(\mathrm{V}(\mathrm{CO})_6, \mathrm{Cr}(\mathrm{CO})_5, \mathrm{Cu}(\mathrm{CO})_3,\)\(\operatorname{Mn}(\mathrm{CO})_5, \mathrm{Fe}(\mathrm{CO})_5,\left[\mathrm{Co}(\mathrm{CO})_3\right]^{3-},\left[\mathrm{Cr}(\mathrm{CO})_4\right]^{4-}\), and \(\operatorname{Ir}(\mathrm{CO})_3\), the total number of species isoelectronic with \(\mathrm{Ni}(\mathrm{CO})_4\) is ________.
[Given, atomic number:\(\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Mn}=25,\) \(\mathrm{Fe}=26, \mathrm{Co}=27, \mathrm{Ni}=28, \mathrm{Cu}=29,\) \(\mathrm{Ir}=77\)]

At \(25^{\circ} \mathrm{C}\), the concentration of \(\mathrm{H}^{+}\)ions in \(1.00 \times 10^{-3} \mathrm{M}\) aqueous solution of a weak monobasic acid having acid dissociation constant \(\left(K_a\right)=4.00 \times 10^{-11}\) is \(\boldsymbol{X} \times 10^{-7} \mathrm{M}\). The value of \(\boldsymbol{X}\) is _____ .
Use: Ionic product of water \(\left(K_w\right)=1.00 \times 10^{-14}\) at \(25^{\circ} \mathrm{C}\)

In the Young's double slit experiment using a monochromatic light of wavelength $\lambda$, the path difference ( in terms of an integer $n$ ) corresponding to any point having half the peak intensity is