The desired product X can be prepared by reacting the major product of the reactions in LIST-I with one or more appropriate reagents in LIST-II.
(given, order of migratory aptitude: aryl > alkyl hydrogen)

	LIST-I		LIST -II
A)		P)	${\mathrm{I}}_2,\mathrm{NaOH}$
B)		Q)	$\left[\mathrm{Ag}{\left({\mathrm{NH}}_3\right)}_2\mathrm{OH}\right]$
C)		R)	Fehling solution
D)		S)	$\mathrm{H}\mathrm{C}\mathrm{H}\mathrm{O},\mathrm{N}\mathrm{a}\mathrm{O}\mathrm{H}$
		T)	$\mathrm{NaOBr}$

The correct statement(s) pertaining to the adsorption of a gas on a solid surface is(are)

The standard enthalpies of formation of $C{O}_2\left(g\right)$ ${\text{, H}}_2\text{O}\left(\mathit{\text{l}}\right)$ and glucose (s) at $25^{\text{o}}C$ are $-\text{400 kJ}/\text{mol}$, $-\text{300 kJ}/\text{mol}$ and $-\text{1300 kJ}/\text{mol}$, respectively. The standard enthalpy combustion per gram of glucose at $25^{\text{o}}C$ is $\left(\Delta H_f^0=-1300kJmo{l}^{-}for\text{glucose}\right)$

The $1^{\mathrm{st}}$, $2^{\mathrm{nd}}$ and the $3^{\mathrm{rd}}$ ionization enthalpies, ${\mathrm{I}}_1, {\mathrm{I}}_2$ and ${\mathrm{I}}_3$, of four atoms with atomic numbers $\mathrm{n}, \mathrm{n}+1, \mathrm{n}+2,$ and $\mathrm{n}+3,$ where $\mathrm{n}<10,$ are tabulated below. What is the value of $\mathrm{n}$?

Atomic number	Ionization Enthalpy (kJ/mol)
	${\mathrm{I}}_1$	${\mathrm{I}}_2$	${\mathrm{I}}_3$
$\mathrm{n}$	$1681$	$3374$	$6050$
$\mathrm{n}+1$	$2081$	$3952$	$6122$
$\mathrm{n}+2$	$496$	$4562$	$6910$
$\mathrm{n}+3$	$738$	$1451$	$7733$

Native silver metal forms a water soluble complex with a dilute aqueous solution of \(\mathrm{NaCN}\) in the presence of

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Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper include chalcanthite \(\left(\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}\right)\), atacamite \(\left(\mathrm{Cu}_2 \mathrm{Cl}(\mathrm{OH})_3\right)\), cuprite \(\left(\mathrm{Cu}_2 \mathrm{O}\right)\), copper glance \(\left(\mathrm{Cu}_2 \mathrm{~S}\right)\) and malachite \(\left(\mathrm{Cu}_2(\mathrm{OH})_2 \mathrm{CO}_3\right)\). However, 80\% of the world copper production comes from the ore chalcopyrite \(\left(\mathrm{CuFeS}_2\right)\). The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.
Question:
In self-reduction, the reducing species is

The IUPAC name of \(\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_4\right]\left[\mathrm{NiCl}_4\right]\) is

Lines \(L_1: y-x=0\) and \(L_2: 2 x+y=0\) intersect the line \(L_3: y+2=0\) at \(P\) and \(Q\), respectively. The bisector of the acute angle between \(L_1\) and \(L_2\) intersects \(L_3\) at \(R\).
Statement I The ratio \(P R: R Q\) equals \(2 \sqrt{2}: \sqrt{5}\).
Statement II In any triangle, bisector of an angle divides the triangle into two similar triangles.

A compound \(\mathrm{M}_{\mathrm{p}} \mathrm{X}_{\mathrm{q}}\) has cubic close packing (ccp) arrangement of \(\mathrm{X}\). Its unit cell structure is shown below. The empirical formula of the compound is

A field line is shown in the figure. This field cannot represent

An electrochemical cell is fueled by the combustion of butane at 1 bar and 298 K . Its cell potential is \(\frac{\boldsymbol{X}}{\boldsymbol{F}} \times 10^3\) volts, where \(\boldsymbol{F}\) is the Faraday constant. The value of \(\boldsymbol{X}\) is \(\qquad\) .
Use : Standard Gibbs energies of formation at 298 K are : \(\Delta_f G_{\mathrm{CO}_2}^{\circ}=-394 \mathrm{~kJ} \mathrm{~mol}^{-1}\);
\(\Delta_f G_{\text {water }}^{\circ}=-237 \mathrm{~kJ} \mathrm{~mol}^{-1} ; \Delta_f G_{\text {butane }}^{\circ}\) \(=-18 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

One mole of an ideal monoatomic gas undergoes two reversible processes $(\mathrm{A}\to \mathrm{B}$ and $\mathrm{B}\to \mathrm{C})$ as shown in the given figure:

$\mathrm{A}\to \mathrm{B}$ is an adiabatic process. If the total heat absorbed in the entire process $(\mathrm{A}\to \mathrm{B}$ and $\mathrm{B}\to \mathrm{C})$ is ${\mathrm{RT}}_2\ln 10$, the value of $2{\mathrm{logV}}_3$ is
[Use molar heat capacity of the gas at constant pressure, ${\mathrm{C}}_{\mathrm{p},\mathrm{m}}=\frac{5}{2}\mathrm{R}$]

Statement I Band gap in germanium is small.
Statement II The energy spread of each germanium atomic energy level is infinitesimally small.