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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

Which of the following statements/ relationships is not correct in thermodynamic changes ?

  1. A \(\Delta U\, = 0\) (isothermal reversible expansion of a gas)
  2. B \(w =  - nRT\,\ln \frac{{{V_2}}}{{{V_1}}}\) ( isothermal reversible expansion of an ideal gas)
  3. C \(w =   nRT\,\ln \frac{{{V_2}}}{{{V_1}}}\) (isothermal reversible expansion of an ideal gas)
  4. D For a system of constant volume heat involved directly changes to internal energy.  
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Correct Answer

(C) \(w =   nRT\,\ln \frac{{{V_2}}}{{{V_1}}}\) (isothermal reversible expansion of an ideal gas)

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For isothermal reversible expansion \(w = - nRT\,\ln \frac{{{V_2}}}{{{V_1}}}\)
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