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JEE Mains · Chemistry · STD 12 - 2. Electrochemistry

The product obtained from the electrolytic oxidation of acidified sulphate solution, is:

  1. A \(\mathrm{HO}_{2} \mathrm{SOSO}_{2} \mathrm{H}\)
  2. B \(\mathrm{HO}_{3} \mathrm{SOOSO}_{3} \mathrm{H}\)
  3. C \(\mathrm{HSO}_{4}^{-}\)
  4. D \(\mathrm{HO}_{3} \mathrm{SOSO}_{3} \mathrm{H}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(\mathrm{HO}_{3} \mathrm{SOOSO}_{3} \mathrm{H}\)

Step-by-step Solution

Detailed explanation

anode: \(2 \mathrm{SO}_{4}^{-2}(\mathrm{aq}) \rightarrow\left(\mathrm{S}_{2} \mathrm{O}_{8}\right)^{-2}+2 \mathrm{e}^{-}\) Cathode : \(2 \mathrm{H}^{2}+2 \mathrm{e}^{-} \rightarrow \mathrm{H}_{2}(\mathrm{~g})\) Electrolysis of concentrated solution of acidified sulphate solution…
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