JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
Select the option with correct property.
- A \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\) and \(\left[\mathrm{NiCl}_4\right]^{2-}\) both diamagnetic
- B \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\) and \(\left[\mathrm{NiCl}_4\right]^{2-}\) both paramagnetic
- C \(\left[\mathrm{NiCl}_4\right]^{2-}\) diamagnetic, \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\) paramagnetic
- D \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\) diamagnetic, \(\left[\mathrm{NiCl}_4\right]^{2-}\) paramagnetic
Answer & Solution
Correct Answer
(D) \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\) diamagnetic, \(\left[\mathrm{NiCl}_4\right]^{2-}\) paramagnetic
Step-by-step Solution
Detailed explanation
\(\left[\mathrm{Ni}(\mathrm{CO})_4\right] \rightarrow\) diamagnetic, \(\mathrm{sp}^3\) hybridisation, number of unpaired electrons \(=0\) \(\left[\mathrm{NiCl}_4\right]^{2-}, \rightarrow\) paramagnetic, \(\mathrm{sp}^3\) hybridisation, number of unpaired electrons \(=2\)
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