ExamBro
ExamBro
JEE Mains · Chemistry · STD 12 - 3. Chemical kinetics

\(N_2O_5\) decomposes to \(NO_2\) and \(O_2\) and follows first order kinetics . After \(50\, minutes\), the pressure inside the vessel increases from \(50\, mm\,Hg\) to \(87 .5\, mm \,Hg\). The pressure of the gaseous mixture after \(100\, minutes\) at constant temperature will be ........... \(mm\,Hg\)

  1. A \(136.25\)
  2. B \(106.25\)
  3. C \(175.0\)
  4. D \(116.25\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(106.25\)

Step-by-step Solution

Detailed explanation

\({N_2}{O_5}\, \to \,2N{O_2}\, + \,\frac{1}{2}{O_2}\) At \(t=0\) \(50\) \(0\) \(0\) At \(t=50\,min\) \(50-p_1\) \(2p_1\) \(\frac {p_1}{2}\) Total pressure at \(50\,\min\) \(=\,50-p_1+2p_1+\frac {p_1}{2}=87.5\) \(50+\frac {3p_1}{2}=87.5\) \(\frac{{3{p_1}}}{2}\, = \,37.5\)…
Same subject
Explore more questions on app
From JEE Mains
Explore more questions on app