JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
Match List \(I\) with List \(II\)
| List \(I\) Complex | List \(II\) Crystal Field splitting energy \(\left(\Delta_0\right)\) |
| \(A\) \(\left[ Ti \left( H _2 O \right)_6\right]^{2+}\) | \(I\) \(-1.2\) |
| \(B\) \(\left[ V \left( H _2 O \right)_6\right]^{2+}\) | \(II\) \(-0.6\) |
| \(C\) \(\left[ Mn \left( H _2 O \right)_6\right]^{3+}\) | \(III\) \(0\) |
| \(D\) \(\left[ Fe \left( H _2 O \right)_6\right]^{3+}\) | \(IV\) \(-0.8\) |
- A \(A-II, B-IV, C-I, D-III\)
- B \(A-IV, B-I, C-II, D-III\)
- C \(A-IV, B-I, C-III, D-II\)
- D \(A-II, B-IV, C-III, D-I\)
Answer & Solution
Correct Answer
(B) \(A-IV, B-I, C-II, D-III\)
Step-by-step Solution
Detailed explanation
(A) \({\left[ Ti \left( H _2 O \right)_6\right]^{2+}}\) \(Ti ^{2+} \Rightarrow 3 d ^2 4 s ^0\) \(t _{2 g } e ^{-}=2\) \(e _{ g } e ^{-}=0\) \(CFSE =[-0.4 \times 2+0.6 \times 0] \Delta_0\) \(-0.8\,\Delta\) (B) \({\left[ V \left( H _2 O \right)_6\right]^{2+}}\)…
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