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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

Match List \(I\) with List \(II\)
List \(I\) Complex List \(II\) \(CFSE(\Delta_0)\)
\(A\) \(\left[ Cu \left( NH _3\right)_6\right]^{2+}\) \(I\) \(-0.6\)
\(B\) \(\left[\operatorname{Ti}\left( N _2 O \right)_6\right]^{3+}\) \(II\) \(-2.0\)
\(C\) \(\left[ Fe ( CN )_6\right]^{3-}\) \(III\) \(-1.2\)
\(D\) \(\left[ NiF _6\right]^{4-}\) \(IV\) \(-0.4\)
Choose the correct answer from the options given below:

  1. A \(A-I, B-IV, C-II, D-III\)
  2. B \(A-II, B-III, C-I, D-IV\)
  3. C \(A-I, B-II, C-IV, D-III\)
  4. D \(A-III, B-IV, C-I, D-II\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(A-I, B-IV, C-II, D-III\)

Step-by-step Solution

Detailed explanation

CFSE \(=\left(-0.4 nt _{2 g }+0.6 n _{ eg }\right) \Delta_0\) \(nt _{2 g }=\) number of electrons in \(t _{2 g }\) orbital \(n_{ eg }=\) number of electrons in eg orbital
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