JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
Match List \(I\) with List \(II\)
| List \(I\) Complex | List \(II\) \(CFSE(\Delta_0)\) |
| \(A\) \(\left[ Cu \left( NH _3\right)_6\right]^{2+}\) | \(I\) \(-0.6\) |
| \(B\) \(\left[\operatorname{Ti}\left( N _2 O \right)_6\right]^{3+}\) | \(II\) \(-2.0\) |
| \(C\) \(\left[ Fe ( CN )_6\right]^{3-}\) | \(III\) \(-1.2\) |
| \(D\) \(\left[ NiF _6\right]^{4-}\) | \(IV\) \(-0.4\) |
- A \(A-I, B-IV, C-II, D-III\)
- B \(A-II, B-III, C-I, D-IV\)
- C \(A-I, B-II, C-IV, D-III\)
- D \(A-III, B-IV, C-I, D-II\)
Answer & Solution
Correct Answer
(A) \(A-I, B-IV, C-II, D-III\)
Step-by-step Solution
Detailed explanation
CFSE \(=\left(-0.4 nt _{2 g }+0.6 n _{ eg }\right) \Delta_0\) \(nt _{2 g }=\) number of electrons in \(t _{2 g }\) orbital \(n_{ eg }=\) number of electrons in eg orbital
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