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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

If enthalpy of atomisation for \(\mathrm{Br}_{2(l)}\) is \(\mathrm{x}\; \mathrm{kJ} / \mathrm{mol}\) and bond enthalpy for \(\mathrm{Br}_{2}\) is \(y \;\mathrm{kJ} / \mathrm{mol}\), the relation between them

  1. A is \(x = y\)
  2. B is \(x < y\)
  3. C does not exist
  4. D is \(x > y\)
Verified Solution

Answer & Solution

Correct Answer

(D) is \(x > y\)

Step-by-step Solution

Detailed explanation

Enthalpy of atomisation of \(\mathrm{Br}_{2}(l)\) \(\mathrm{Br}_{2}(l) \stackrel{\Delta \mathrm{H}_{\mathrm{vap}}}{\longrightarrow} \mathrm{Br}_{2}(\mathrm{g}) \stackrel{\Delta \mathrm{H}_{\mathrm{BE}}}{\longrightarrow} 2 \mathrm{Br}(\underline{\mathrm{g}})\)…
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