JEE Mains · Chemistry · STD 12 - 3. Chemical kinetics

For the reaction \(2 \mathrm{H}_{2}(\mathrm{g})+2 \mathrm{NO}(\mathrm{g}) \rightarrow \mathrm{N}_{2}(\mathrm{g})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{g})\) the observed rate expression is, rate \(=\mathrm{k}_{\mathrm{f}}[\mathrm{NO}]^{2}\left[\mathrm{H}_{2}\right] .\) The rate expression of the reverse reaction is

A \(\mathrm{k}_{\mathrm{b}}\left[\mathrm{N}_{2}\right]\left[\mathrm{H}_{2} \mathrm{O}\right]^{2} /[\mathrm{NO}]\)
B \(\mathrm{k}_{\mathrm{b}}\left[\mathrm{N}_{2}\right]\left[\mathrm{H}_{2} \mathrm{O}\right]\)
C \(\mathrm{k}_{\mathrm{b}}\left[\mathrm{N}_{2}\right]\left[\mathrm{H}_{2} \mathrm{O}\right]^{2}\)
D \(\mathrm{k}_{\mathrm{b}}\left[\mathrm{N}_{2}\right]\left[\mathrm{H}_{2} \mathrm{O}\right]^{2} /\left[\mathrm{H}_{2}\right]\)

Verified Solution

Answer & Solution

Correct Answer

(D) \(\mathrm{k}_{\mathrm{b}}\left[\mathrm{N}_{2}\right]\left[\mathrm{H}_{2} \mathrm{O}\right]^{2} /\left[\mathrm{H}_{2}\right]\)

Step-by-step Solution

Detailed explanation

\(\mathrm{K}_{\mathrm{eq}}=\frac{\mathrm{k}_{\mathrm{f}}}{\mathrm{k}_{\mathrm{b}}}=\frac{\left[\mathrm{N}_{2}\right]\left[\mathrm{H}_{2} \mathrm{O}\right]^{2}}{\left[\mathrm{H}_{2}\right]^{2}[\mathrm{NO}]^{2}}\) At equilibrium \(\mathrm{r}_{\mathrm{f}}=\mathrm{r}_{\mathrm{b}}\)…

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

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Match List\(-I\) with List\(-II\) :

List\(-I\) (Species)	List\(-II\) (Number of lone pairs of electrons on the central atom)
\((a)\) \(\mathrm{XeF}_{2}\)	\((i)\, 0\)
\((b)\) \(\mathrm{XeO}_{2} \mathrm{~F}_{2}\)	\((ii) \,1\)
\((c)\) \(\mathrm{XeO}_{3} \mathrm{~F}_{2}\)	\((iii) \,2\)
\((d)\) \(\mathrm{XeF}_{4}\)	\((iv) \,3\)

Choose the most appropriate answer from the options given below:

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