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JEE Mains · Chemistry · STD 11 -p-Block elements - I

Evaluate the following statements related to group \(14\) elements for their correctness. \((A)\)Covalent radius decreases down the group from \(\mathrm{C}\) to \(\mathrm{Pb}\) in a regular manner. \((B)\) Electronegativity decreases from \(\mathrm{C}\) to \(\mathrm{Pb}\) down the group gradually. \((C)\) Maximum covalence of \(\mathrm{C}\) is \(4\) whereas other elements can expand their covalence due to presence of \(d\) orbitals. \((D)\) Heavier elements do not form \(\mathrm{p} \pi-p \pi\) bonds. \((E)\) Carbon can exhibit negative oxidation states. Choose the correct answer from the options given below:

  1. A \((C), (D)\) and \((E)\) Only
  2. B \((A)\) and \((B)\) Only
  3. C \((A), (B)\) and \((C)\) Only
  4. D \((C)\) and \((D)\) Only
Verified Solution

Answer & Solution

Correct Answer

(A) \((C), (D)\) and \((E)\) Only

Step-by-step Solution

Detailed explanation

\((A)\) Down the group; radius increases \((B)\) EN does not decrease gradually from \(\mathrm{C}\) to \(\mathrm{Pb}\). \((C)\) Correct. \((D)\) Correct. \((E)\) Range of oxidation state of carbon ; \(-4\) to \(+4\)
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