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JEE Mains · Chemistry · STD 11 - 8.3. Organic chemistry purification and characterization

Match the organic compounds in column \(-I\) with the Lassaigne's test results in column \(-II\) appropriately
Column \(-I\) Column \(-II\)
\((A)\) Aniline \((i)\) Red colour with \(FeCl_3\)
\((B)\) Benzene sulfonic acid \((ii)\) Violet colour with sodium nitroprusside
\((C)\) Thiourea \((iii)\) Blue colour with hot and acidic solution of \(FeSO_ 4\)

  1. A \(A - (ii); B - (iii) ; C - (i)\)
  2. B \(A - (iii); B - (i) ; C - (ii)\)
  3. C \(A - (iii); B - (ii) ; C - (i)\)
  4. D \(A - (ii); B - (i) ; C - (iii)\)
Verified Solution

Answer & Solution

Correct Answer

(C) \(A - (iii); B - (ii) ; C - (i)\)

Step-by-step Solution

Detailed explanation

\((c)\) In Lassaigne's test, fusion with sodium take place and following species formed respectively. \((a)\) Aniline \(\to \) \(CN^-\) \((b)\) Benzene sulfonic acid \(\to \) (figure) \((c)\) Thiourea \(\to \) \(S^{2-}\) Reaction of \(CN^-\) with hot and acidic solution of…
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