JEE Mains · Chemistry · STD 11 - 8.3. Organic chemistry purification and characterization
Match the organic compounds in column \(-I\) with the Lassaigne's test results in column \(-II\) appropriately
| Column \(-I\) | Column \(-II\) |
| \((A)\) Aniline | \((i)\) Red colour with \(FeCl_3\) |
| \((B)\) Benzene sulfonic acid | \((ii)\) Violet colour with sodium nitroprusside |
| \((C)\) Thiourea | \((iii)\) Blue colour with hot and acidic solution of \(FeSO_ 4\) |
- A \(A - (ii); B - (iii) ; C - (i)\)
- B \(A - (iii); B - (i) ; C - (ii)\)
- C \(A - (iii); B - (ii) ; C - (i)\)
- D \(A - (ii); B - (i) ; C - (iii)\)
Answer & Solution
Correct Answer
(C) \(A - (iii); B - (ii) ; C - (i)\)
Step-by-step Solution
Detailed explanation
\((c)\) In Lassaigne's test, fusion with sodium take place and following species formed respectively. \((a)\) Aniline \(\to \) \(CN^-\) \((b)\) Benzene sulfonic acid \(\to \) (figure) \((c)\) Thiourea \(\to \) \(S^{2-}\) Reaction of \(CN^-\) with hot and acidic solution of…
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