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JEE Mains · Chemistry · STD 12 - 3. Chemical kinetics

Decomposition of A is a first order reaction at T(K) and is given by \(A(g) \rightarrow B(g) + C(g)\). In a closed 1 L vessel, 1 bar A(g) is allowed to decompose at T(K). After 100 minutes, the total pressure was 1.5 bar. What is the rate constant (in \(min^{-1}\)) of the reaction? (\(log 2 = 0.3\))

  1. A \(6.9 \times 10^{-1}\)
  2. B \(6.9 \times 10^{-3}\)
  3. C \(6.9 \times 10^{-2}\)
  4. D \(6.9 \times 10^{-4}\)
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Answer & Solution

Correct Answer

(B) \(6.9 \times 10^{-3}\)

Step-by-step Solution

Detailed explanation

\(A_{g} \rightarrow B_{g} + C_{g}\) \(1 \quad - \quad -\) \(1- P \quad P \quad P\) \(P_{\text {total }}=1+P\) \(1.5=1+P\) \(P =0.5\) \(K =\frac{1}{100} \ln \frac{1}{0.5}\) \(=\frac{0.693}{100}\) \(=6.9 \times 10^{-3} min^{-1}\)
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