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JEE Mains · Chemistry · STD 11 - 8.3. Organic chemistry purification and characterization

During the qualitative analysis of salt with cation \(y ^{2+}\), addition of a reagent \(( X )\) to alkaline solution of the salt gives a bright red precipitate. The reagent \(( X )\) and the cation \(\left( y ^{2+}\right)\) present respectively are .... .

  1. A Dimethylglyoxime and \(Ni ^{2+}\)
  2. B Dimethylglyoxime and \(Co ^{2+}\)
  3. C Nessler's reagent and \(Hg ^{2+}\)
  4. D Nessler's reagent and \(Ni ^{2+}\)
Verified Solution

Answer & Solution

Correct Answer

(A) Dimethylglyoxime and \(Ni ^{2+}\)

Step-by-step Solution

Detailed explanation

\(Ni ^{2+}+ DMG ^{-} \rightarrow\left[ Ni ( DMG )_{2}\right] \downarrow\) (Bright red precipitate)
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