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JEE Mains · Chemistry · STD 12 - 4. d and f- block elements

Correct statements from the following are
A. Potassium dichromate is an oxidising agent and it oxidises \(FeSO_4\) to \(Fe_2(SO_4)_3\) in acidic medium.
B. Sodium dichromate can be used as primary standard in volumetric estimation.
C. \(CrO_4^{2-}\) and \(Cr_2O_7^{2-}\) are interconvertible in aqueous solution by varying the \(pH\) of the solution.
D. \(Cr\)-\(O\)-\(Cr\) bond angle in \(Cr_2O_7^{2-}\) is \(126^\circ\).

Choose the correct answer from the options given below:

  1. A A, B and C Only
  2. B A, C and D Only
  3. C A and C Only
  4. D B and D Only
Verified Solution

Answer & Solution

Correct Answer

(B) A, C and D Only

Step-by-step Solution

Detailed explanation

Statement A is correct. Potassium dichromate acts as a strong oxidising agent in acidic medium and oxidises \(Fe^{2+}\) to \(Fe^{3+}\), converting \(FeSO_4\) to \(Fe_2(SO_4)_3\). Statement B is incorrect. Sodium dichromate is deliquescent (absorbs moisture from the atmosphere),…
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