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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

An ideal gas, \(\overline{\mathrm{C}}_{\mathrm{V}}=\frac{5}{2} \mathrm{R}\), is expanded adiabatically against a constant pressure of \(1 \mathrm{~atm}\) untill it doubles in volume. If the initial temperature and pressure is \(298 \mathrm{~K}\) and \(5 \mathrm{~atm}\), respectively then the final temperature is _______ \(\mathrm{K}\) (nearest integer). [ \(\overline{\mathrm{C}}_{\mathrm{V}}\) is the molar heat capacity at constant volume]

  1. A \(273\)
  2. B \(274\)
  3. C \(277\)
  4. D \(280\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(274\)

Step-by-step Solution

Detailed explanation

\(\Delta \mathrm{U}=\mathrm{q}+\mathrm{w}(\mathrm{q}=0)\) \(\mathrm{nC}_{\mathrm{V}} \Delta \mathrm{T}=-\mathrm{P}_{\mathrm{ext}}\left(\mathrm{V}_2-\mathrm{V}_1\right)\) \(\mathrm{V}_2=2 \mathrm{~V}_1\)…
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