The complex showing a spin-only magnetic moment of \(2.82\) B.M. is

A monoatomic ideal gas undergoes a process in which the ratio of \(P\) to \(V\) at any instant is constant and equals to 1 . What is the molar heat capacity of the gas?

The substituents \(R_{1}\) and \(R_{2}\) for nine peptides are listed in the table given below. How many of these peptides are positively charged at \(\mathrm{pH}=7.0\) ?

\(\begin{array}{|c|c|c|}\hline Peptide & \mathbf{R}_{\mathbf{1}} & \mathbf{R}_{\mathbf{2}} \\\hline I & \mathrm{H} & \mathrm{H} \\\hline II & \mathrm{H} & \mathrm{CH}_{3} \\\hline III & \mathrm{CH}_{2} \mathrm{COOH} & \mathrm{H} \\\hline IV & \mathrm{CH}_{2} \mathrm{CONH}_{2} & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} \\\hline V & \mathrm{CH}_{2} \mathrm{CONH}_{2} & \mathrm{CH}_{2} \mathrm{CONH}_{2} \\\hline VI & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} \\\hline VII & \mathrm{CH}_{2} \mathrm{COOH} & \mathrm{CH}_{2} \mathrm{CONH}_{2} \\\hline VIII & \mathrm{CH}_{2} \mathrm{OH} & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} \\\hline IX & \left(\mathrm{CH}_{2}\right)_{4} \mathrm{NH}_{2} & \mathrm{CH}_{3} \\\hline\end{array}\)

Consider the strong electrolytes ${\mathrm{Z}}_{\mathrm{m}}{\mathrm{X}}_{\mathrm{n}}, {\mathrm{U}}_{\mathrm{m}}{\mathrm{Y}}_{\mathrm{p}}$ and ${\mathrm{V}}_{\mathrm{m}}{\mathrm{X}}_{\mathrm{n}}$. Limiting molar conductivity of ${\mathrm{U}}_{\mathrm{m}}{\mathrm{Y}}_{\mathrm{p}}$ and ${\mathrm{V}}_{\mathrm{m}}{\mathrm{X}}_{\mathrm{n}}$ are $250$ and $440 \mathrm{S} {\mathrm{cm}}^2 {\mathrm{mol}}^{-1}$, respectively. The value of $\left(\mathrm{m}+\mathrm{n}+\mathrm{p}\right)$ is Given:

Ion	\(Z ^{ n +}\)	\(U ^{ p +}\)	\(V ^{ n +}\)	\(X ^{ m }\)	\(Y ^{ m -}\)
\(\lambda^0(\text{S cm} ^2\) \(\text{mol}^{-1})\)	50.0	25.0	100.0	80.0	100.0

${\lambda }^0$ is the limiting molar conductivity of ions The plot of molar conductivity $\left(\Lambda \right)$ of ${\mathrm{Z}}_{\mathrm{m}}{\mathrm{X}}_{\mathrm{n}}$ vs ${\mathrm{c}}^{\frac{1}{2}}$ is given below. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.

The electrochemical cell shown below is a concentration cell. \(\mathrm{M} \mid \mathrm{M}^{2+}\) (saturated solution of a sparingly soluble salt, \(\left.\mathrm{MX}_{2}\right) \| \mathrm{M}^{2 \perp}\left(0.001 \mathrm{~mol} \mathrm{dm}^{-3}\right) \mid \mathrm{M}\).
The emf of the cell depends on the difference in concentrations of \(\mathrm{M}^{2+}\) ions at the two electrodes. The emf of the cell at \(298 \mathrm{~K}\) is \(0.059 \mathrm{~V}\).
Question:
The value of \(\Delta \mathrm{G}\left(\mathrm{kJ} \mathrm{mol}^{-1}\right)\) for the given cell is (take 1 \(\mathrm{F}=96500 \mathrm{Cmol}^{-1}\) )

$\mathrm{F}{\mathrm{e}}^{3+}$ is reduced to $\mathrm{F}{\mathrm{e}}^{2+}$ by using

The reactivity of compound Z with different halogens under appropriate conditions is given below:

The observed pattern of electrophilic substitution can be explained by

The mass \(M\) shown in the figure oscillates in simple harmonic motion with amplitude \(A\). The amplitude of the point \(P\) is

A circular insulated copper wire loop is twisted to form two loops of area $A$ and $2A$ as shown in the figure. At the point of crossing the wires remain electrically insulated from each other. The entire loop lies in the plane (of the paper). A uniform magnetic field $\overrightarrow{B}$ points into the plane of the paper. At $t=0$ , the loop starts rotating about the common diameter as axis with a constant angular velocity in the magnetic field. Which of the following options is/are correct?

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p-amino-N, N-dimethylaniline is added to a strongly acidic solution of \(X\). The resulting solution is treated with a few drops of aqueous solution of \(Y\) to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of \(Y\) with the reagent potassium hexacyanoferrate(II) leads to the formation of an intense blue precipitate. The precipitate dissolves an excess addition of the reagent. Similarly, treatment of the solution of \(Y\) with the solution of potassium hexacyanoferrate(III) leads to a brown colouration due to the formation of \(Z\).
Question:
The compound \(Z\), is

The equilibrium \(2 \mathrm{Cu}^{\mathrm{I}} \rightleftharpoons \mathrm{Cu}^0+\mathrm{Cu}^{\text {II }}\) in aqueous medium at \(25^{\circ} \mathrm{C}\) shifts towards the left in the presence of

Let $f:\left(0, \pi \right)\to \mathbb{R}$ be a twice differentiable function such that $\underset{t\to x}{\lim }\frac{f\left(x\right)\sin t-f\left(t\right)\sin x}{t-x}={\sin }^{2}x$ for all $x\in \left(0, \pi \right)$. If $f\left(\frac{\pi }{6}\right)=-\frac{\pi }{12}$, then which of the following statement(s) is (are) TRUE ?

The coefficients of three consecutive terms of ${\left(1+\text{x}\right)}^{\text{n}+5}$ are in the ratio $\text{5 : 10 : 14}$. Then $\text{n} =$