A monoatomic ideal gas undergoes a process in which the ratio of \(P\) to \(V\) at any instant is constant and equals to 1 . What is the molar heat capacity of the gas?

Hydrogen peroxide in its reaction with KIO₄ and NH₂OH respectively, is acting as a

The total number of cyclic structural as well as stereoisomers possible for a compound with the molecular formula \(=\mathrm{C}_5 \mathrm{H}_{10}\) is

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\(\mathbf{X}\) and \(\mathbf{Y}\) are two volatile liquids with molar weights of \(10 \mathrm{~g} \mathrm{~mol}^{-1}\) and \(40 \mathrm{~g} \mathrm{~mol}^{-1}\) respectively. Two cotton plugs, one soaked in \(\mathbf{X}\) and the other soaked in \(\mathbf{Y}\), are simultaneously placed at the ends of a tube of length \(L=24 \mathrm{~cm}\), as shown in the figure. The tube is filled with an inert gas at \(1\) atmosphere pressure and a temperature of \(300 \mathrm{~K}\). Vapours of \(\mathbf{X}\) and \(\mathbf{Y}\) react to form a product which is first observed at a distance \(\mathbf{d} \mathrm{~cm}\) from the plug soaked in \(\mathbf{X}\). Take \(\mathbf{X}\) and \(\mathbf{Y}\) to have equal molecular diameters and assume ideal behaviour for the inert gas and the two vapours.



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The experimental value of \(\mathbf{d}\) is found to be smaller than the estimate obtained using Graham's law. This is due to

The option(s) with only amphoteric oxides is(are)

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Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator automobiles.
A solution \(M\) is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixtrue is \(0.9\)
Given Freezing point depression constant of water \(\left(k^{\text {water }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\)
Freezing point depression constant of ethanol \(\left(k_f^{\text {ethanol }}\right)=2.0 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of water \(\left(k_b^{\text {water }}\right)=0.52 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of ethanol \(\left(k_b^{\text {ethanol }}\right)=1.2 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Standard freezing point of water \(=273 \mathrm{~K}\)
Standard freezing point of ethanol \(=155.7 \mathrm{~K}\)
Standard boiling point of water \(=373 \mathrm{~K}\)
Standard boiling point of ethanol \(=351.5 \mathrm{~K}\)
Vapour pressure of pure water \(=328 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Vapour pressure of pure ethanol \(=40 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Molecular weight of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\)
Molecular weight of ethanol \(=46 \mathrm{~g} \mathrm{~mol}^{-1}\)
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Question:
The vapour pressure of the solution \(M\) is

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The coordination number of \(\mathrm{Ni}^{2+}\) is 4 .
\(\mathrm{NiCl}_2+\mathrm{KCN}\) (excess) \(\rightarrow A\) (cyano complex)
\(\mathrm{NiCl}_2+\) conc. \(\mathrm{HCl}\) (excess) \(\rightarrow B\) (chloro complex)
Question:
Predict the magnetic nature of \(A\) and \(B\) are

Consider the following statements related to colloids.
(I) Lyophobic colloids are not formed by simple mixing of dispersed phase and dispersion medium.
(II) For emulsions, both the dispersed phase and the dispersion medium are liquid.
(III) Micelles are produced by dissolving a surfactant in any solvent at any temperature.
(IV) Tyndall effect can be observed from a colloidal solution with dispersed phase having the same refractive index as that of the dispersion medium.
The option with the correct set of statements is

The isotope ${}_5{}^{12}B$ having a mass 12.014 u undergoes $\beta$ - decay to ${}_6{}^{12}C . {}_6{}^{12}C$ has an excited state of the nucleus $\left({}_6{}^{12}{C}^{*}\right)$ at 4.041 MeV above its ground state. If ${}_5{}^{12}B$ decays to ${}_6{}^{12}{C}^{*},$ the maximum kinetic energy of the $\beta$ - particle in units of MeV is ( $1\mu =931.5 Me\frac{V}{c^2},$ where c is the speed of light in vacuum).

Let two non-collinear unit vectors \(\mathbf{a}\) and \(\hat{\mathbf{b}}\) form an acute angle.
A point \(P\) moves so that at any time \(t\) the position vector \(\mathbf{O P}\) (where, \(O\) is the origin) is given by \(\mathbf{a} \cos t+\hat{\mathbf{b}} \sin t\). When \(P\) is farthest from origin \(O\), let \(M\) be the length of \(\mathbf{O P}\) and \(\hat{\mathbf{u}}\) be the unit vector along \(\mathbf{O P}\). Then,

A debate club consists of 6 girls and 4 boys. A team of 4 members is to be selected from this club including the selection of a captain (from among these 4 members) for the team. If the team has to include at most one boy, then the number of ways of selecting the team is

The quadratic equation $\mathrm{p}\left(\mathrm{x}\right)\mathrm{ }=\mathrm{ }0$ with real coefficients has purely imaginary roots. Then the equation $\mathrm{p}\left(\mathrm{p}\right(\mathrm{x}\left)\right)\mathrm{ }=\mathrm{ }0$ has

Aqueous solutions of \(\mathrm{HNO}_3, \mathrm{KOH}\), \(\mathrm{CH}_3 \mathrm{COOH}\), and \(\mathrm{CH}_3 \mathrm{COONa}\) of identical concentrations are provided. The pair(s) of solutions which form a buffer upon mixing is(are)