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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

संकुलों \((A) - (D)\) के प्रचक्रण-मात्र चुम्बकीय आघूर्णों का सही क्रम है  \((A)\) \(Ni ( CO )_{4}\) \((B)\) \(\left[ Ni \left( H _{2} O \right)_{6}\right] Cl _{2}\) \((C)\) \(Na _{2}\left[ Ni ( CN )_{4}\right]\) \((D)\) \(PdCl _{2}\left( PPh _{3}\right)_{2}\)

  1. A \((\mathrm{A}) \approx(\mathrm{C}) \approx(\mathrm{D}) < (\mathrm{B})\)
  2. B \((\mathrm{A}) \approx(\mathrm{C}) < (\mathrm{B}) \approx(\mathrm{D})\)
  3. C \((\mathrm{C}) < (\mathrm{D}) < (\mathrm{B}) < (\mathrm{A})\)
  4. D \((\mathrm{C}) \approx(\mathrm{D}) < (\mathrm{B}) < (\mathrm{A})\)
Verified Solution

Answer & Solution

Correct Answer

(A) \((\mathrm{A}) \approx(\mathrm{C}) \approx(\mathrm{D}) < (\mathrm{B})\)

Step-by-step Solution

Detailed explanation

\(\left[\mathrm{Ni}(\mathrm{CO})_{4}\right] \quad \mu_{\mathrm{m}}=0 \mathrm{B}. \mathrm{M}\) \({\left[\mathrm{Ni}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}}\quad {\mu_{\mathrm{m}}=2.8 \mathrm{B} . \mathrm{M}}\)…
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