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JEE Mains · Chemistry · STD 12 - 2. Electrochemistry

सेल पर विचार कीजिए:- \(Pt ( s )\left| H _2( s )( latm )\right| H ^{+}\left( aq ,\left[ H ^{+}\right]=1\right)|| Fe ^{3+}( aq ), Fe ^{2+}( aq ) \mid \operatorname{Pt}( s )\) दिया है : \(E _{ Fe ^{3+} / e ^{2 *}}^0=0.771\,V\) અને \(E _{ H ^{+}+\frac{1}{2} H _2}^0=0\,V , T =298\,K\) यदि सेल का विभव \(0.712 \mathrm{~V}\) है तो \(\mathrm{Fe}^{2+}\) तथा \(\mathrm{Fe}^{2+}\) की सान्द्रता का अनुपात है______________  (निकटतम पूर्णांक में)

  1. A \(100\)
  2. B \(10\)
  3. C \(105\)
  4. D \(852\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(10\)

Step-by-step Solution

Detailed explanation

\(\frac{1}{2} H _2( g )+ Fe ^{3+} \text { (aq.) } \longrightarrow H ^{+}( aq )+ Fe ^{2+}( aq .)\) \(E = E ^{\circ}-\frac{0.059}{1} \log \frac{\left[ Fe ^{2+}\right]}{\left\lfloor Fe ^{3+}\right\rfloor}\)…
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