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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

\(K_3[Co(CN)_6]\) માં ધાતુની કઈ \(d-\) કક્ષકો જે સીધી રીતે લિગાન્ડની સામે હશે? 

  1. A \(d_{xy}\) અને \(d_{x^2 - y^2}\)
  2. B  \(d_{x^2 - y^2}\) અને \(d_{z^2}\)
  3. C \(d_{xz} ,d_{yz}\) અને \(d_{z^2}\)
  4. D \(d_{xy}, d_{xz}\), અને \(d_{yz}\)
Verified Solution

Answer & Solution

Correct Answer

(B)  \(d_{x^2 - y^2}\) અને \(d_{z^2}\)

Step-by-step Solution

Detailed explanation

Given \(K_3[Co(CN)_6]\) is inner orbital complex with hybridization \(d^2sp^3\) and octahedral geometry. Ligands are approaching metal along the axes. Hence, \(d_{x^2 - y^2} , d_{z^2}\) orbitals are directly in front of the ligands
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