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JEE Mains · Chemistry · STD 12 -8.1. Aldehydes and ketones

'\(x\)' is the product which is obtained from benzene by reacting it with carbon monoxide and hydrogen chloride in the presence of cuprous chloride. '\(y\)' is the major product obtained from the benzene by reacting it with ethanoyl chloride in the presence of anhydrous AlCl\(_3\). Product (major) obtained by heating \(x\) and \(y\) in the presence of alkali is \(z\). Total number of \(\pi\) (pi) electrons in \(z\) is ________.

  1. A 4
  2. B 8
  3. C 16
  4. D 32
Verified Solution

Answer & Solution

Correct Answer

(C) 16

Step-by-step Solution

Detailed explanation

Benzene reacts with \(CO\) and \(HCl\) in the presence of \(CuCl\) to give benzaldehyde (\(x\)) via the Gattermann-Koch reaction. Benzene reacts with ethanoyl chloride (\(CH_3COCl\)) in the presence of anhydrous \(AlCl_3\) to give acetophenone (\(y\)) via Friedel-Crafts…