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JEE Mains · Chemistry · STD 12 - 4. d and f- block elements

Which of the following statements is false ?

  1. A \(Na_2Cr_2O_7\) is less soluble than \(K_2Cr_2O_7\)
  2. B \(Na_2Cr_2O_7\) is primary standard in volumetry
  3. C \(CrO_4^{2-}\) is tetrahedral in shape
  4. D \(CrO_7^{2-}\) has a \(Cr- O- Cr\) bond
Verified Solution

Answer & Solution

Correct Answer

(A) \(Na_2Cr_2O_7\) is less soluble than \(K_2Cr_2O_7\)

Step-by-step Solution

Detailed explanation

\(Na_2Cr_2O_7\) is used as primary standard in volumetry Hydration energy of \(Na^+\) is greater then \(K^+\). Because of smaller size of \(Na^+\) , \(Na_2Cr_2O_7\) is more soluble than \(K_2Cr_2O_7\).
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