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JEE Mains · Chemistry · STD 12 - 2. Electrochemistry

Resistance of a conductivity cell (cell constant \(129 \;m ^{-1}\) ) filled with \(74.5\; ppm\) solution of \(KCl\) is \(100\; \Omega\) (labelled as solution 1). When the same cell is filled with \(KCl\) solution of \(149 \;ppm\), the resistance is \(50\; \Omega\) (labelled as solution 2). The ratio of molar conductivity of solution \(1\) and solution \(2\) is i.e. \(\frac{\wedge_{1}}{\wedge_{2}}=x \times 10^{-3}\). The value of \(x\) is (Nearest integer) Given, molar mass of \(KCl\) is \(74.5 g mol ^{-1}\)

  1. A \(1000\)
  2. B \(2000\)
  3. C \(3000\)
  4. D \(4000\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(1000\)

Step-by-step Solution

Detailed explanation

\(\frac{\ell}{ A }=129\; m ^{-1}\) \(KCl\) solution \(1\) : \(74.5\; ppm , R _{1}=100\; \Omega\) \(KCl\) solution \(2\) : \(149\; ppm , R _{2}=50 \;\Omega\) \(149\;ppm , R _{2}=50 \;\Omega\) Here,…
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