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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

Which one of the following complexes is violet in colour?

  1. A \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4-}\)
  2. B \(\left[\mathrm{Fe}(\mathrm{SCN})_{6}\right]^{4-}\)
  3. C \(\mathrm{Fe}_{4}\left[\mathrm{Fe}\left(\mathrm{CN}_{6}\right)\right]_{3} \cdot \mathrm{H}_{2} \mathrm{O}\)
  4. D \(\left[\mathrm{Fe}(\mathrm{CN})_{5} \mathrm{NOS}\right]^{4}\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(\left[\mathrm{Fe}(\mathrm{CN})_{5} \mathrm{NOS}\right]^{4}\)

Step-by-step Solution

Detailed explanation

\((A)\) \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{4-} \rightarrow\) Pale yellow solution \((B)\) \(\left[\mathrm{Fe}(\mathrm{SCN})_{6}\right]^{4-} \rightarrow\) Blood red colour \((C)\)…
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