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JEE Mains · Chemistry · STD 11 - 8.3. Organic chemistry purification and characterization

Match List \(I\) with List \(II\).
List-\(I\) (Compound)List-\(II\) (Colour)
\((A)\) \(\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3 \cdot \mathrm{xH}_2 \mathrm{O}\)\((I)\) Violet
\((B)\)\(\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NOS}\right]^{4-}\)\((II)\) Blood Red
\((C)\)\([\mathrm{Fe}(\mathrm{SCN})]^{2+}\)\((III)\)Prussian Blue
\((D)\)\(\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4 \cdot 12 \mathrm{MoO}_3\)\((IV)\) Yellow
Choose the correct answer from the options given below :

  1. A \(A-III, B-I, C-II, D-IV\)
  2. B \(A-IV, B-I, C-II, D-III\)
  3. C \(A-II, B-III, C-IV, D-I\)
  4. D \(A-I, B-II, C-III, D-IV\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(A-III, B-I, C-II, D-IV\)

Step-by-step Solution

Detailed explanation

\(\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3 \cdot \mathrm{xH}_2 \mathrm{O} \rightarrow \text { Prussian Blue }\) \({\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NOS}\right]^{4-} \rightarrow \text { Violet }}\)…
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