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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

Amongst \(FeCl _{3} \cdot 3 H _{2} O , \quad K _{3}\left[ Fe ( CN )_{6}\right]\) and \(\left[ Co \left( NH _{3}\right)_{6}\right] Cl _{3}\), the spin-only magnetic moment value of the inner-orbital complex that absorbs light at shortest wavelength is \(B.M.\,......\) [nearest integer]

  1. A \(5\)
  2. B \(0.2\)
  3. C \(2\)
  4. D \(20\)
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Answer & Solution

Correct Answer

(C) \(2\)

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Detailed explanation

\(\left[ Fe \left( H _{2} O \right)_{3} Cl _{3}\right], \quad \underbrace{ K _{3}\left[ Fe ( CN )_{6}\right],\left[ Co \left( NH _{3}\right)_{6}\right] Cl _{3}}_{\text {inner orbital complexes }}\) \(K _{3}\left[ Fe ( CN )_{6}\right]\) has more value of \(\Delta_{0}\) than that…
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