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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

The oxidation states of iron atoms in compounds \((A),\) \((B)\) and \((C),\) respectively, are \(x,\) \(y\) and \(z.\) The sum of \(x, y\) and \(z\) is........ \((A)\) \(\left. Na _{4}\left[ Fe ( CN )_{5} NOS \right)\right]\) \((B)\) \(Na _{4}\left[ FeO _{4}\right]\) \((C)\) \(\left[ Fe _{2}( CO )_{9}\right]\)

  1. A \(14\)
  2. B \(10\)
  3. C \(8\)
  4. D \(6\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(6\)

Step-by-step Solution

Detailed explanation

\(\left( A \right)\,N{a_4}\left[ {\mathop F\limits^x e{{\left( {CN} \right)}_5}\left( {NOS} \right)} \right]\) \((+1) 4+x+(-1) 5+(-1) 1=0\) \(x=+2\) \(\left( B \right)\,N{a_4}\left[ {\mathop {Fe{O_4}}\limits^y } \right]\) \((+1) 4+y+(-2) 4=0\) \(y=+4\)…
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