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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

Indicate the complex/complex ion which did not show any geometrical isomerism :

  1. A \(\left[\mathrm{CoCl}_{2}(\mathrm{en})_{2}\right]\)
  2. B \(\left[\mathrm{Co}(\mathrm{CN})_{5}(\mathrm{NC})\right]^{3-}\)
  3. C \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3}\left(\mathrm{NO}_{2}\right)_{3}\right]\)
  4. D \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Cl}_{2}\right]^{+}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(\left[\mathrm{Co}(\mathrm{CN})_{5}(\mathrm{NC})\right]^{3-}\)

Step-by-step Solution

Detailed explanation

(1) \(\left[\mathrm{CoCl}_{2}(\mathrm{en})_{2}\right]\) show Cis-trans isomerism (2) \(\left[\mathrm{Co}(\mathrm{CN})_{5}(\mathrm{NC})\right]^{-3}\) can't Show \(G.I.\) (3) \(\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{3}\left(\mathrm{NO}_{2}\right)_{3}\right]\) Show fac…
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