JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
In which of the following order the given complex ions are arranged correctly with respect to their decreasing spin only magnetic moment? \((i)\) \(\left[ FeF _{6}\right]^{3-}\) \((ii)\) \(\left[ Co \left( NH _{3}\right)_{6}\right]^{3+}\) \((iii)\) \(\left[ NiCl _{4}\right]^{2-}\) \((iv)\) \(\left[ Cu \left( NH _{3}\right)_{4}\right]^{2+}\)
- A \(( i ) > ( iii ) > ( iv ) > ( ii )\)
- B \((ii) > ( iii) > ( i ) > ( iv )\)
- C \((iii) > ( iv ) > ( ii ) > ( i )\)
- D \(( ii ) > ( i ) > ( iii ) > ( iv )\)
Answer & Solution
Correct Answer
(A) \(( i ) > ( iii ) > ( iv ) > ( ii )\)
Step-by-step Solution
Detailed explanation
Complex \((i)\) \(\left[ FeF _{6}\right]^{3-} Fe ^{3+} \Rightarrow[ Ar ] 3 d ^{5}, F ^{-}\) is \(WFL\) \(n =5, \quad \mu=\sqrt{35}\, B .M.\) \((ii)\) \(\left[ Co \left( NH _{3}\right)_{6}\right]^{3+} \Rightarrow Co ^{3+}[ Ar ] 3 d ^{6}, NH _{3}\) is \(SFL\) \(n =0, \quad \mu=0\)…
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