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JEE Mains · Chemistry · STD 12 - 2. Electrochemistry

Copper reduces \(NO _{3}^{-}\) into \(NO\) and \(NO _{2}\) depending uponthe concentration of \(HNO _{3}\) insolution. (Assuming fixed \(\left[ Cu ^{2+}\right]\) and \(\left. P _{ NO }= P _{ NO _{2}}\right),\) the \(HNO _{3}\) concentration at which the thermodynamic tendency for reduction of \(NO _{3}^{-}\) into \(NO\) and \(NO _{2}\) by copper is same is \(10^{ x }\, M\). The value of \(2 x\) is ...... . \(\left[\right.\) Given \(, E_{C u^{2+} / C u}^{o}=0.34\, V , E _{ NO _{3}^{-} / NO_2 }^{\circ}=0.96\, V\) (Rounded-off to the nearest integer) \(E _{ NO _{3} / NO _{2}}^{\circ}=0.79 \,V\) and at \(298 \,K\)  \(\left.\frac{ RT }{ F }(2.303)=0.059\right]\)

  1. A \(1\)
  2. B \(2\)
  3. C \(3\)
  4. D \(4\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(1\)

Step-by-step Solution

Detailed explanation

If the partial pressure of \(NO\) and \(NO _{2}\) gas is taken as \(1\) bar, then Answer is \(4,\) else the question is bonus. \(NO _{3}^{-}+4 H ^{+}+3 e ^{-} \longrightarrow NO +2 H _{2} O\)…
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