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JEE Mains · Chemistry · STD 12 - 4. d and f- block elements

In chromyl chloride, the number of d-electrons present on chromium is same as in (Given at no. of \(Ti : 22, V : 23, Cr : 24, Mn : 25, Fe : 26)\)

  1. A \(T_i\,(III)\)
  2. B \(Fe\, (III)\)
  3. C \(V\, (IV)\)
  4. D \(Mn\,(VII)\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(Mn\,(VII)\)

Step-by-step Solution

Detailed explanation

In \(CrO _2 Cl _2\) oxidation state of \(Cr\) is +6 \(Cr ( VI )=[ Ar ]^{18} 3 d ^0\) \(Mn ( VII )=[ Ar ]^{18} 3 d ^0\) \(Fe ( III )=[ Ar ]^{18} 3 d ^5\) \(Ti ( III )=[ Ar ]^{18} 3 d ^1\) \(V ( IV )=[ Ar ]^{18} 3 d ^1\) Hence \(Cr\) (VI) and \(Mn\) (VII) have same \(d^0\)…
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