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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

If \(5\) moles of an ideal gas expands from \(10 \mathrm{~L}\) to a volume of \(100 \mathrm{~L}\) at \(300 \mathrm{~K}\) under isothermal and reversible condition then work, \(w\), is \(-x \mathrm{~J}\). The value of \(x\) is _____. (Given \(\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\) )

  1. A \(28719\)
  2. B \(28721\)
  3. C \(28722\)
  4. D \(28725\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(28721\)

Step-by-step Solution

Detailed explanation

It is isothermal reversible expansion, so work done negative \(\mathrm{W}=-2.303 \mathrm{nRT} \log \left(\frac{\mathrm{V}_2}{\mathrm{~V}_1}\right)\) \(=-2.303 \times 5 \times 8.314 \times 300 \log \left(\frac{100}{10}\right)\) \(=-28720.713 \mathrm{~J}\)…
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