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JEE Mains · Chemistry · STD 12 - 9. Amines

Given below are two statements : one is labelled as Assertion \((A)\) and the other is labelled as Reason \((R)\). Assertion \((A)\) : Experimental reaction of \(CH _{3} Cl\) with aniline and anhydrous \(AlCl _{3}\) does not give \(o\) and \(p-methylaniline\). Reason \((R)\) : The - \(NH _{2}\) group of aniline becomes deactivating because of salt formation with anhydrous \(AlCl _{3}\) and hence yields \(m\)-methyl aniline as the product. In the light of the above statements, choose the most appropriate answer from the options given below.

  1. A Both \((A)\) and \((R)\) are true and \((R)\) is the correct explanation of \((A)\).
  2. B Both \((A)\) and \((R)\) are true but \((R)\) is not the correct explanation of \((A)\).
  3. C \((A)\) is true, but \((R)\) is false.
  4. D \((A)\) is false, but \((R)\) is true.
Verified Solution

Answer & Solution

Correct Answer

(C) \((A)\) is true, but \((R)\) is false.

Step-by-step Solution

Detailed explanation

Friedel Craft Alkylation does not occur on this deactivated ring.
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