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JEE Mains · Chemistry · STD 11 - 8.4. Organic chemistry reaction mechanism

Consider the following molecules/species:

\((x)\) tropone, \((y)\) acetone, \((z)\) acetate ion
The correct order of carbon – oxygen double bond length is:

  1. A \(x>y>z\)
  2. B \(y>z>x\)
  3. C \(z>x>y\)
  4. D \(x>z>y\)
Verified Solution

Answer & Solution

Correct Answer

(C) \(z>x>y\)

Step-by-step Solution

Detailed explanation

In acetone \((y)\), the carbon-oxygen bond is a localized double bond with a bond order of approximately \(2\). In the acetate ion \((z)\), there are two equivalent resonance structures that delocalize the negative charge equally over both oxygen atoms. This results in a…
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