A sample of n-octane \((1.14 \mathrm{~g})\) was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is \(5 \mathrm{~kJ} \mathrm{~K}^{-1}\). As a result of combustion reaction, the temperature of the calorimeter is increased by 5 K. The magnitude of the heat of combustion of octane at constant volume is ______ \(\mathrm{kJ} \mathrm{mol}^{-1}\) (nearest integer).

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.