JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry
A reaction at \(1\,bar\) is non-spontaneous at low temperature but becomes spontaneous at high temperature. Identify the correct statement about the reaction among the following
- A \(\Delta H\) is negative while \(\Delta S\) is positive
- B Both \(\Delta H\) and are \(\Delta S\) negative
- C \(\Delta H\) is positive while \(\Delta S\) is negative
- D Both \(\Delta H\) and \(\Delta S\) are positive
Answer & Solution
Correct Answer
(D) Both \(\Delta H\) and \(\Delta S\) are positive
Step-by-step Solution
Detailed explanation
\(\Delta G\, = \,\Delta H - T\Delta S\) For a spontaneous reaction \(\Delta G = -ve\) which is possible when both \(\Delta H\) and \(\Delta S\) are positive at high temperature and hence the reaction becomes spontaneous.
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- The correct combination isJEE Mains 2018 Hard
- Galvanization is applying a coating of :JEE Mains 2016 Easy
- The reaction of zinc with dilute and concentrated nitric acid, respectively, produces :JEE Mains 2016 Hard
- The first transition series metal ' M ' has the highest enthalpy of atomisation in its series. One of its aquated ion \(\left(\mathrm{M}^{\mathrm{n} \dagger}\right)\) exists in green colour. The nature of the oxide formed by the above \(\mathrm{M}^{\mathrm{n}-}\) ion is _______.JEE Mains 2025 Medium
- Ammonolysis of Alkyl halides followed by the treatment with \(NaOH\) solution can be used to prepare primary, secondary and tertiary amines. The purpose of \(NaOH\) in the reaction is :JEE Mains 2021 Medium
- Find out the statements which are not true.
A. Resonating structure with more number of covalent bonds and lesser charge separation are more stable.
B. In electromeric effect, an unsaturated system shows + E effect with nucleophile and - E effect with electrophile.
C. Inductive effect is responsible for high melting point, boiling point and dipole moment of polar compounds.
D. The greater the number of alkyl groups attached to the doubly bonded carbon atoms, higher is the heat of hydrogenation.
E. Stability of carbanion increases with the increase in s-character of the carbon carrying the negative charge.
Choose the correct answer from the options given below.JEE Mains 2026 Easy
More PYQs from JEE Mains
- The resistance of a conductivity cell with cell constant \(1.14 \,\mathrm{~cm}^{-1}\), containing \(0.001\, \mathrm{M}\, \mathrm{KCl}\) at \(298\, \mathrm{~K}\) is \(1500 \,\Omega\). The molar conductivity of \(0.001\, \mathrm{M}\, \mathrm{KCl}\) solution at \(298\, \mathrm{~K}\) in \(\mathrm{S} \,\mathrm{cm}^{2}\, \mathrm{~mol}^{-1}\) is ...... . (Integer answer)JEE Mains 2021 Easy
- A wind-10.Powered generator converts wind energy into electrical energy. Assume that the generator converts a fixed fraction of the wind energy intercepted by its blades into electrical energy. For wind speed \(v\), the electrical 10.Power output will be most likely proportional toJEE Mains 2013 Hard
- For \(0<\theta<\pi / 2\), if the eccentricity of the hyperbola \(\mathrm{x}^2-\mathrm{y}^2 \operatorname{cosec}^2 \theta=5\) is \(\sqrt{7}\) times eccentricity of the ellipse \(x^2 \operatorname{cosec}^2 \theta+y^2=5\), then the value of \(\theta\) is :JEE Mains 2024 Medium
- Let \(a,b,c\; \in R.\) If \(f\left( x \right) = a{x^2} + bx + c\) is such that \(a + b + c = 3\) and \(f\left( {x + y} \right) = f\left( x \right) + f\left( y \right) + xy,\) \(\forall x,y \in R,\) then \(\mathop \sum \limits_{n = 1}^{10} f\left( n \right)\) is equal to :JEE Mains 2017 Hard
- For the following Friedel Craft's alkylation reaction, which of the statements are correct?

A. Major product is n-propyl benzene.
B. iso-propyl carbocation intermediate is also generated.
C. Multiple substitution is inevitable.
D. Introducing electron-donating substituent on benzene will not produce any alkyl benzene.
Choose the correct answer from the options given below:JEE Mains 2026 Medium - The number of solutions, of the equation \(\mathrm{e}^{\sin x}-2 e^{-\sin x}=2\) isJEE Mains 2024 Hard