The correct statement(s) regarding defects in solids is (are)

Ozonolysis of ${\mathrm{ClO}}_2$ produces an oxide of chlorine. The average oxidation state of chlorine in this oxide is ______ .

The electrochemical extraction of aluminium from bauxite ore involves

The pair(s) of diamagnetic ions is(are)

Among the following, the surfactant that will form micelles in aqueous solution at the lowest molar concentration at ambient conditions is

All the compounds listed in Column I react with water. Match the result of the respective reactions with the appropriate options listed in Column II.

Paragraph:

The amount of energy required to break a bond is same as the amount of energy released when the same bond is formed. In gaseous state, the energy required for homolytic cleavage of a bond is called Bond Dissociation Energy (BDE) or Bond Strength. BDE is affected by \(s\)-character of the bond and the stability of the radicals formed. Shorter bonds are typically stronger bonds. BDEs for some bonds are given below:












Question:
Correct match of the \(\mathbf{C}-\mathbf{H}\) bonds (shown in bold) in Column \(\mathbf{J}\) with their BDE in Column \(\mathbf{K}\) is

Paragraph:

Football teams \(T_{1}\) and \(T_{2}\) have to play two games against each other. It is assumed that the outcomes of the two games are independent. The probabilities of \(T_{1}\) winning, drawing and losing a game against \(T_{2}\) are \(\frac{1}{2}, \frac{1}{6}\) and \(\frac{1}{3}\), respectively. Each team gets \(3\) points for a win, \(1\) point for a draw and \(0\) point for a loss in a game. Let \(X\) and \(Y\) denote the total points scored by teams \(T_{1}\) and \(T_{2}\), respectively, after two games.


Question:

\(P(X>Y)\) is

Paragraph :

Consider an evacuated cylindrical chamber of height \(h\) having rigid conducting plates at the ends and an insulating curved surface as shown in the figure. A number of spherical balls made of a light weight and soft material and coated with a conducting material are placed on the bottom plate. The balls have a radius \(r \ll h\). Now a high voltage source \((HV)\) is connected across the conducting plates such that the bottom plate is at \(+V_{0}\) and the top plate at \(-V_{0} .\) Due to their conducting surface, the balls will get charged, will become equipotential with the plate and are repelled by it. The balls will eventually collide with the top plate, where the coefficient of restitution can be taken to be zero due to the soft nature of the material of the balls. The electric field in the chamber can be considered to be that of a parallel plate capacitor. Assume that there are no collisions between the balls and the interaction between them is negligible. (Ignore gravity)



Question :

Which one of the following statements is correct?

Paragraph :
A thermally insulating cylinder has a thermally insulating and frictionless movable partition in the middle, as shown in the figure below. On each side of the partition, there is one mole of an ideal gas, with specific heat at constant volume, \(C_{V}=2 R\). Here, \(R\) is the gas constant. Initially, each side has a volume \(V_{0}\) and temperature \(T_{0}\). The left side has an electric heater, which is turned on at very low power to transfer heat \(Q\) to the gas on the left side. As a result the partition moves slowly towards the right reducing the right side volume to \(V_{0} / 2\). Consequently, the gas temperatures on the left and the right sides become \(T_{L}\) and \(T_{R}\), respectively. Ignore the changes in the temperatures of the cylinder, heater and the partition.

Question :
The value of $\frac{T_R}{T_0}$ is:

The area of the region between the curves \(y=\sqrt{\frac{1+\sin x}{\cos x}}\) and \(y=\sqrt{\frac{1-\sin x}{\cos x}}\) bounded by the lines \(x=0\) and \(x=\frac{\pi}{4}\) is

Let $f:\left(0, 1\right)\to \mathrm{ℝ}$ be the function defined as $f\left(x\right)=\sqrt{n}$ if $x\in [\frac{1}{n+1}, \frac{1}{n})$ where $n\in \mathrm{\mathbb{N}}$. Let $g:\left(0, 1\right)\to \mathrm{ℝ}$ be a function such that ${\int }_{x^2}^x\sqrt{\frac{1-t}{t}}dt<g\left(x\right)<2\sqrt{x}$ for all $x\in \left(0, 1\right)$. Then $\underset{x\to 0}{\lim }f\left(x\right) g\left(x\right)$

For the cell $\mathrm{Zn} \left(\mathrm{s}\right)\left|{\mathrm{ZnSO}}_4 \left(\mathrm{aq}\right)\right|\left|{\mathrm{CuSO}}_4 \left(\mathrm{aq}\right)\right|\mathrm{Cu} \left(\mathrm{s}\right)$, when the concentration of ${\mathrm{Zn}}^{2+}$ is $10$ times the concentration of ${\mathrm{Cu}}^{2+}$, the expression for $\mathrm{\Delta G} \left(\mathrm{in}\mathrm{ }\mathrm{J}\mathrm{ }{\mathrm{mol}}^{-1}\right)$ is
$[\mathrm{F}=$Faraday's constant, $\mathrm{R}=$universal gas constant, $\mathrm{T}=$temperature, ${\mathrm{E}}^{\mathrm{o}}\mathrm{cell}=1.1\mathrm{V}]$